Kinetics and Mechanism of (CF 3 ) 2 CHOCH 3 Reaction with OH Radicals in an Environmental Reaction Chamber
β Scribed by Chen, L.; Kutsuna, S.; Tokuhashi, K.; Sekiya, A.; Tamai, R.; Hibino, Y.
- Book ID
- 126116704
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 143 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClο£ΎCCl~2~ (__k__~1~), CF~3~CClο£ΎCClCF~3~ (__k__~2~) and CF~3~CFο£ΎCFCF~3~ (__k__~3~). Experiments were carried out at (298Β±2) K and atmospheric pressure using ultrapure nitr
The reaction of CF, with NO, was studied at 296 2 2 K using two different absolute techniques Absolute rate constants of ( I 6 ? 0.3) X lo-" and ( 2 1-03+07) X lo-" cm3 molecule-' s-' were derived by IR fluorescence and UV absorption spectroscopy, respectively The reaction proceeds via two reaction