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Kinetics and mechanism of anionic polymerization of ε-caprolactone in the presence of additions of protonic acids

✍ Scribed by G.A. Estrina; S.P. Davtyan; B.A. Rozenberg

Book ID
118966326
Publisher
Elsevier Science
Year
1979
Weight
406 KB
Volume
21
Category
Article
ISSN
0032-3950

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Ring-opening polymerization of ε-caprola
Ring-opening polymerization of ε-caprolactone in the presence of dicarboxylic acids
✍ Qijin Zhang; Bin Wang; Kulun Hong; Qingren Zhu 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 307 KB

## Abstract The ring‐opening polymerization of ε‐caprolactone (ε‐CL) has been investigated in the presence of succinic acid in nitrogen atmosphere at 225°C. Analysis of the resultant polymers suggests that the poly(ε‐caprolactone) (PCL) obtained has two terminal carboxylic groups. VPO, ^1^H NMR and