Kinetics and mechanism of an unique hydrolysis reaction of (hexafluoroacetylacetonato)bis(ethylenediamine)cobalt(III) in aqueous solution
β Scribed by Y. Kitamura; R. Eldik
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 299 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0340-4285
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## Abstract Kinetics of reduction of the surfactant complex ions, __cis__βchloro/bromo (dodecylamine)bis(ethylenediamine)cobalt(III) by iron(II) in aqueous solution was studied at 303, 308, and 313 K by spectrophotometry method under pseudoβfirstβorder conditions, using an excess of the reductant.
The kinetics of aquation of cis-[Co(en)z(H20)Br ] 2 + and cis-[Cr(en)2(H20)Br] 2+ (en = ethylenediamine) were investigated in aqueous mixtures of MeOH, EtOH, i-PrOH and t-BuOH. The values of transfer functions corresponding to the transfer of reactants and activated complex from water to the solvent