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Kinetics and equilibria of thiol/disulfide interchange reactions of selected biological thiols and related molecules with oxidized glutathione

โœ Scribed by Keire, David A.; Strauss, Erin; Guo, Wei; Noszal, Bela; Rabenstein, Dallas L.

Book ID
126223213
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
704 KB
Volume
57
Category
Article
ISSN
0022-3263

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Reversibility and regioselectivity in thiol/disulfide interchange of tocinoic acid with glutathione in lyophilized solids
โœ Lei Zhang; Todd D. Williams; Elizabeth M. Topp ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 120 KB

Thiol/disulfide interchange is one of the most common routes of aggregation of lyophilized protein drug products, but the mechanisms of the reaction in the solid state have not been established. Here, we report perturbations in thiol/disulfide interchange upon lyophilization, using tocionic acid (cy