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Kinetic study on the effect of solvent in ‘vapor-phase’ Beckmann rearrangement of cyclohexanone oxime on silicalite-1

✍ Scribed by Takayuki Komatsu; Takeya Maeda; Tatsuaki Yashima

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
162 KB
Volume
35-36
Category
Article
ISSN
1387-1811

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On the Beckmann rearrangement of ketoximes: A kinetic study in trifluoromethanesulfonic acid
✍ N. C. Marziano; L. Ronchin; C. Tortato; O. Tonon; R. Bertani 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract The formation and the destruction of an intermediate involved in the Beckmann rearrangement of 2,4,6‐trimethylacetophenone oxime have been studied in concentrated trifluoromethanesulfonic acid by kinetic and spectroscopic measurements. Observed (__k__~obs~) and thermodynamic rate consta