Kinetic Study of the Reactions of Chlorine Atoms and Cl 2•- Radical Anions in Aqueous Solutions. II. Toluene, Benzoic Acid, and Chlorobenzene †
✍ Scribed by Mártire, Daniel O.; Rosso, Janina A.; Bertolotti, Sonia; Le Roux, Galo Carrillo; Braun, André M.; Gonzalez, Mónica C.
- Book ID
- 120815615
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 116 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A laser photolysis-long path laser absorption (LP-LPLA) experiment has been used to determine the rate constants for H-atom abstraction reactions of the dichloride radical anion (Cl 2 Ϫ ) in aqueous solution. From direct measurements of the decay of Cl 2 Ϫ in the presence of different reactants at p
The kinetics of the gas-phase reaction of C1 atoms with CF31 have been studied relative to the reaction of C1 atoms with CH4 over the temperature range 271-363 K. Using k(C1 + CH4) = 9.6 X exp(-2680/RT) cm3 molecule-' s-', we derive k(C1 + CF3I) = 6.25 X lo-'' exp(-2970/RT) in which E , has units of