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Kinetic study of the reaction of diisocyanates with the nitro derivatives of polyols

✍ Scribed by N.L. Solodova; L.M. Kozlov; V.I. Burmistrov


Book ID
118357235
Publisher
Elsevier Science
Year
1965
Weight
274 KB
Volume
7
Category
Article
ISSN
0032-3950

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The rate constants for the reactions of 4-halomethyl-3-nitrobenzoic acids, the nonnitro derivatives, and their ethyl esters with arylthiolates were measured at different temperatures. It was found that the retardation in rate constants compared to benzyl halides is due to the electrostatic repulsion