Kinetic study of the reaction between iodide and N-chloramines
✍ Scribed by J. M. Antelo; F. Arce; J. Campos; M. Parajó
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 382 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
✦ Synopsis
We carried out a kinetic study of the reaction between iodide ion and various primary N-chlorarnines and found it to be First-order in the latter Experiments also showed the rate constant f o r t h e reaction to be directly proportional to the iodide and hydrogen ion concentrations The influence of the buffer concentration reveals the presence of general acid catalysis processes 0 1996 lohn Wiley &Sons, Inc
📜 SIMILAR VOLUMES
Ascorbic acid present in natural products is often analyzed by its reducing effect on 2,6-dichlorophenolindophenol (DCPI). In case of coexistence of Fe(II) in natural samples and if oxalic acid is used for their extraction and stabilization, a significant interference is observed. The reaction of Fe
The kinetics of oxidation of Norfloxacin [1-ethyl-6-fluoro-1,4-dihydro-4-oxo-7-(lpiperazinyl)-3-quinoline carboxylic acid] by chloramine-B and N-chlorobenzotriazole has been studied in aqueous acetic acid medium (25% v/v) in the presence of perchloric acid at 323 K. For both the oxidants, the reacti
The effects of the kind and amount of oxirane (propylene or ethylene oxide), the amount of triethylamine catalyst, and the temperature on the reaction with N,N,N,N,NЉ-pentakis(hydroxymethyl)melamine (PHMM) in DMSO solution were studied. The changes in the content of reactive groups in the reaction m
Polyethylene terephthalate (PET) was blended with two kinds of co[poly-(ethylene terephthalate-p-oxybenzoate)] (POB-PET) copolyester, designated as P46 and P64, respectively. The PET and POB-PET copolyester were combined in the ratios of 85/15, 70/30, and 50/50. The blends were melt mixed in a Brabe
The chemical reaction involving iodide and nitrite at the surface of platinum disk microelectrodes has been investigated in sulfuric acid medium. Experimental conditions were adjusted to achieve a quasi-®rst order homogeneous catalytic reaction in quiescent solutions and the kinetic rate constant fo