Almtract--A comparative kinetic study of the reactions of three diisocyanates [tolylene diisocyanate (TDI), 3-isocyanatomethyl-3, 5, 5,-trimethylcyclohexyl isocyanate (IPDI) and hexamethylene diisocyanate (HDI)] with a hydroxyl-terminated polybutadiene (R-45M) was carried out in chlorobenzene soluti
β¦ LIBER β¦
Kinetic study of the reaction between a hydroxylated polybutadiene and isocyanates in chlorobenzene, III. Reaction with dimer diacid diisocyanate (DDI)
β Scribed by Fernanda M. B. Coutinho; Marisa G. Rocha
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 253 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0887-624X
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A kinetic study of the reaction between a hydroxyl-terminated polybutadiene (HTPB) and isophorone diisocyanate (IPDI) was carried out in the bulk state by using quantitative Fourier transform infrared (FTIR) spectroscopy. The reaction is shown to obey a second-order rate law, being first order in bo