Kinetic study of the oxidation of 1,4-dihydropyridines with chloranil
โ Scribed by R. A. Dommisse; J. A. Lepoivre; F. C. Alderweireldt
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 205 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0037-9646
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The kinetics of oxidation of 1,4-Dioxane (Dio) by Diperiodatonickelate (IV) (DPN) in aqueous alkaline medium at a constant ionic strength of 1.5 mol dm ฯช3 was studied spectrophotometrically. The reaction shows first-order kinetics in [DPN] and less than unit order dependence each in [Dio] and [OH ฯช
The alkaline hydrolysis of p-chloranil or 2,3,5,6-tetrachloro-1,4-benzoquinone (C 6 Cl 4 O 2 , Q) was studied, using stopped flow spectrophotometry and Electron Spin Resonance techniques (E.S.R.). In the present study it was shown for the first time, that a free radical is produced chemically and th