Using the laser photolysis vacuum-UV laser-induced fluorescence 'pump-and-probe' technique, Doppler profiles of H and D atoms from the reaction O(1D) + HD were measured under single-collision conditions, O(aD) atoms were generated by laser photolysis of N20 at 193 nm. With a calibration method using
Kinetic study of the H + IBr reaction: rate constants, branching ratio and yields of excited halogen atoms
β Scribed by I.A. Boriev; E.B. Gordon; A.A. Efimenko
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 399 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We present a kinetic study of the reaction Rb + N20 ---, Rb + N20 kNro by direct spectroscopic monitoring of ground state atomic rubidium in the time domain. Rb(52Sm/2) was generated by the pulsed irradiation of rubidium halide vapors at elevated temperatures in the presence of low concentrations of
Direct ab initio dynamic calculations are performed on the reactions of atomic hydrogen with GeD(n)(CH(3))(4-n) (n = 1-4) over the temperature range 200-2000 K at the PMP4SDTQ/6-311 +G(3df,2p)//MP2/6-31 +G(d) (for n = 2-4) and G2//MP2/6-31 +G(d) (for n = 1) levels. The corresponding k(H)/k(D) ratios
## Abstract The primary quantum yield of Hβatom production in the pulsedβlaser photolysis of hydrazine vapor, N~2~H~4~ + hΞ½ β H + N~2~H~3~, was measured to be (1.01 Β± 0.12) at 193 nm relative to HBr photolysis, and (1.06 Β± 0.16) at 222 nm relative to 248βnm N~2~H~4~ photolysis, in excess He buffer