The gas-phase reaction of NO 3 radicals with isoprene was investigated under flow conditions at 298 K in the pressure range 6.8 Ͻ P(mbar) Ͻ 100 using GC-MS/FID, direct MS, and long-path FT-IR spectroscopy as detection techniques. By means of a relative rate method, the rate constant for the primary
✦ LIBER ✦
Kinetic Study of the Gas Phase Reactions of a Series of Alcohols with the NO 3 Radical
✍ Scribed by Moreno, Alberto; Salgado, M. Sagrario; Martín, M. Pilar; Martínez, Ernesto; Cabañas, Beatriz
- Book ID
- 127060865
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 950 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The kinetics of the reactions of hydroxyl (OH) radicals with 2,3,5‐trimethylphenol (235TMP), 2,3,6‐trimethylphenol (236TMP), 2,4,5‐trimethylphenol (245TMP), 2,4,6‐trimethylphenol (246TMP), and 3,4,5‐trimethylphenol (345TMP) have been investigated at 298 ± 2 K and atmospheric pressure of