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Kinetic study of the formation of meisenheimer complexes : interaction of OH− and CH3O− ions with 3,5-dinitropyridine in water, methanol and their mixtures with dimethylsulfoxide.

✍ Scribed by Robert Schaal; François Terrier; Jean-Claude Halle; Alain-Pierre Chatrousse


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
195 KB
Volume
11
Category
Article
ISSN
0040-4039

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Evidence for complex formation in the re
✍ Richard D. Smith; Jean H. Futrell 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 447 KB

Product distributions for the reactions of CH$ and CDf with methanol, methanol-da, and ethanol studied in a tandemkm CpdOtrOTl resonance mass SpeCtrOmeter are reported. The major reaction pathways may 5c rationalized in terms of 3x1 intermediate species havving a pro&mated ether structure. The react