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Kinetic Study of the Emission of the First Negative System in an Argon-Nitrogen Plasma at Atmospheric Pressure

✍ Scribed by G. Callède; J. Deschamps; J. L. Godart


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
433 KB
Volume
33
Category
Article
ISSN
0005-8025

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✦ Synopsis


Abstract

Quantitative optical spectroscopy measurements of the emission spectra of the N(B^2^∑~u~,)ν′→X^2^∑~g~ν″ transition (first negative system) in an Ar‐N~2~ microwave discharge at atmospheric pressure have allowed determination of the rate coefficient of the production of N molecules in the B^2^ ∑~u~, state with vibrational level ν′ = 0.

The N(B^2^∑~u~, ν′) molecules are produced by the reactionmagnified imagein a surface‐wave‐induced microwave discharge (2450 MHz) sustained in an open‐ended dielectric tube. The rate coefficient K (T) has been obtained for ν′ν″ = 0 for different gas temperatures by varying the incident microwave power. The K~00~(T) values are between 7.10^−10^ and 4.10^−10^ cm^3^ s^−1^ for the temperature range 2500 to 3450K.


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