✦ LIBER ✦

Kinetic study of the condensation of salicylaldehyde with diethyl malonate in a nonpolar solvent catalyzed by secondary amines

✍ Scribed by Szczepan Bednarz; Dariusz Bogdal

Book ID: 102449329
Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 210 KB
Volume: 41
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.20429

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The kinetics of condensation between salicylaldehyde and diethylmalonate in a toluene solution in the presence of secondary amines (i.e., piperidine and 4‐piperidinopiperidine) as catalysts was investigated. It was found that the reaction proceeds via the Knoevenagel mechanism, and the kinetic model was numerically verified. © 2009 Wiley Periodicals, Inc. Int J Chem Kinet 41: 589–598, 2009

📜 SIMILAR VOLUMES

Kinetic study of structuration by conden

Kinetic study of structuration by condensation during the diffusive dilution of a polymer solution with a non-solvent

✍ A.Ye. Chalykh; K.I. Freidgeim; V.I. Alekseyenko 📂 Article 📅 1970 🏛 Elsevier Science ⚖ 549 KB

The condensation reaction of trichlorosi

The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine

✍ N. Furuya; T. Sukawa 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 169 KB

Electrophilic aromatic substitution. 11.

Electrophilic aromatic substitution. 11. A kinetic study of the boron trifluoride-catalyzed benzylation reaction in nonpolar solvents. Kinetic evidence for BF3 catalytic activity involving a fluorine-bridged BF3 dimer

✍ DeHaan, Franklin P.; Chan, Wai H.; Chen, W. David; Ferrara, Daro M.; Giggy, Chri 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 563 KB

A kinetic study by NMR of the benzoin co

A kinetic study by NMR of the benzoin condensation catalyzed by thiazolium salts in mild basic conditions: a second order process in both aldehyde and pre-catalyst.

✍ Francisco López-Calahorra; Raimon Rubires 📂 Article 📅 1995 🏛 Elsevier Science 🌐 French ⚖ 902 KB

Kinetic Resolution of (±)-1-Phenylbutan-

Kinetic Resolution of (±)-1-Phenylbutan-1-ol by Means of CALB-Catalyzed Aminolyses: A Study on the Role of the Amine in the Alcohol Resolution

✍ Eduardo García-Urdiales; Francisca Rebolledo; Vicente Gotor 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB 👁 2 views

ChemInform Abstract: A Kinetic Study by

ChemInform Abstract: A Kinetic Study by NMR of the Benzoin Condensation Catalyzed by Thiazolium Salts in Mild Basic Conditions: A Second Order Process in Both Aldehyde and Pre-Catalyst.

✍ F. LOPEZ-CALAHORRA; R. RUBIRES 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB