Kinetic study of nucleophile specificity in dipeptide synthesis catalyzed by clostridiopeptidase B
โ Scribed by G. Fortier; J. Gagnon
- Book ID
- 115708647
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 557 KB
- Volume
- 276
- Category
- Article
- ISSN
- 0003-9861
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The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะC. In the presence of the catalyst, the experimental rate law
## Abstract RuCl~3~ further catalyzes the oxidation of iodide ion by K~3~Fe(CN)~6~, already catalyzed by hydrogen ions. The rate of reaction, when catalyzed only by hydrogen ions, was separated graphically from the rate when both Ru(III) and H^+^ ions catalyzed the reaction. Reactions studied separ