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Kinetic Study of IO Radical with RO 2 (R = CH 3 , C 2 H 5 , and CF 3 ) Using Cavity Ring-Down Spectroscopy

✍ Scribed by Enami, Shinichi; Yamanaka, Takashi; Hashimoto, Satoshi; Kawasaki, Masahiro; Nakano, Yukio; Ishiwata, Takashi


Book ID
118068183
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
97 KB
Volume
110
Category
Article
ISSN
1089-5639

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Kinetics of the reactions H + C2H4 β†’ C2H
✍ Alfred Sillesen; Emil Ratajczak; Palle Pagsberg πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 527 KB

Formation of methyl radicals via the consecutive reactions H+C2H,+M+C2H,+M ( I ) and H+CLH,+CH,+CH3 (?a) was initiated by pulse radiolysis of IO-100 mbar Hz in the presence of ethylene. The kinetics of CH, were studied by monitoring the transient infrared absorption at the Q( 3, 3) line of the u,=O+