✦ LIBER ✦
Kinetic study of a retro Diels–Alder reaction in a single-pulse shock tube: Decyclization of 1-methylcyclohex-1-ene
✍ Scribed by John M. Simmie
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 277 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The kinetics of the gas‐phase decomposition of 1‐methylcyclohex‐1‐ene has been studied over the temperature range of 1000°–1180° K in a single‐pulse shock tube using a comparative‐rate technique. The retro Diels‐Alder reaction to ethylene and isoprene accounts for the bulk of the products with a rate constant given by