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Kinetic study for the reactions of chlorine atoms with hexamethyldisiloxane, 1,1,3,3-tetramethyldisiloxane, and 1,3-dimethyldisiloxane

✍ Scribed by Alexandros V. Prosmitis; Vassilis C. Papadimitriou; Josef Pola; Panos Papagiannakopoulos

Book ID: 108312399
Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 91 KB
Volume: 344
Category: Article
ISSN: 0009-2614
DOI: 10.1016/s0009-2614(01)00713-8

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## Abstract The hydrogen abstraction reactions of Cl atom with a series of fluorinated alcohols, i.e., CH~3−__n__~F~__n__~CH~2~OH + Cl (__n__ = 1–3) (R1–R3) have been studied systematically by __ab initio__ direct dynamics method and the canonical variational transition state theory (CVT). The pote