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Kinetic study for reactions of nitrate radical (NO3.bul.) with substituted toluenes in acetonitrile solution

✍ Scribed by Ito, Osamu; Akiho, Seiji; Iino, Masashi


Book ID
126146481
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
614 KB
Volume
54
Category
Article
ISSN
0022-3263

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Flash photolysis study for reactions of
✍ Seiji Akiho; Osamu Ito; Masashi Iino πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 454 KB

The rate constants for the reaction of NO3' with sulfur compounds in acetonitrile have been determined by the flash photolysis method. The rate constant for dimethyl sulfone (2.7 x lo4 M-'s-' a t -10Β°C) is larger than that of the deuterium derivative, indicating that NO; abstracts the hydrogen atom