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Kinetic Studies on the Thermal Decomposition of trans -2,3-Dimethyl-1-tri- tert -butylsilyl-1-triisopropylsilylsilirane and the Mechanism of Silylene Generation

✍ Scribed by Jiang, Ping; Trieber, Dwight; Gaspar, Peter P.


Book ID
126800092
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
131 KB
Volume
22
Category
Article
ISSN
0276-7333

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The kinetics of the gas-phase thermal is
✍ Juan C. Ferrero; Eduardo H. Staricco πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 437 KB πŸ‘ 1 views

## Abstract The kinetics of the gas‐phase thermal isomerization between __trans__‐ and __cis__‐1,2‐bis(trifluoromethyl)‐1,2,3,3‐tetrafluorocyclopropane as well as their decomposition to __trans__‐ and __cis__‐perfluoro‐2‐butene, respectively, and CF~2~, was studied in the temperature range of 473–5