Ring-opening radical polymerization has been followed by the flash photolysis method. As a n initiator radical, the arylthiyl radical (ArS') was used; the addition reaction rate constants of ArS' to vinyl monomer containing epoxy-ring such as vinyloxiranes (CH2 = C H C m H 2 ) have been determined a
Kinetic studies on the ring opening polymerization of cyclopentene
✍ Scribed by E. Ceaušescu; A. Cornilescu; M. Dimonie; E. Nicolescu; M. Popescu; S. Coca
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 524 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0323-7648
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## Abstract The kinetics of the anionic ring‐opening polymerization of several cyclodisilazanes substituted with different groups on silicon atoms has been investigated in toluene/tetrahydrofuran (THF) using benzyllithium as initiator. Two different behaviours were observed: for hindered substituen
## Abstract Rate constants of the ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) by microwave heating (MH) and flash conventional heating (FCH) have been measured. The reaction is catalyzed by stannous octanoate (Sn(Oct)~2~). With a microwave power level of 400, 500, 600, 700 an