Kinetic studies of the reactions of some phenyl aryl sulfides with aliphatic amines in dimethyl sulfoxide; the mechanism of base catalysis
โ Scribed by Chamberlin, Rachel A.; Crampton, Michael R.
- Book ID
- 121258279
- Publisher
- Royal Society of Chemistry
- Year
- 1994
- Tongue
- English
- Weight
- 916 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1472-779X
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๐ SIMILAR VOLUMES
## Abstract A variational transitionโstate theory calculation for the reaction of OH radical with dimethyl sulfide (DMS) in the absence of oxygen is presented. The potential energy surface was previously studied and the effects of different levels of theory were analyzed. Here we propose a kinetic
Reactions of morpholine in dimethyl sulphoxide at unsubstituted ring positions of 1,3,5-trinitrobenzene, and phenyl 2,4,64rinitrophenyl ether, yield anionic a-adducts via zwitterionic intermediates. Reactions at the 1- position of phenyl 2,4,64rinitrophenyl ether, phenyl 2,4-dinitronaphthyl ether, a