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Kinetic studies of cyclohexane hydrogenation catalyzed by the Rh(I) compounds with 2-aminopyridine

✍ Scribed by M. Zuber; B. Banaś; F. Pruchnik

Book ID
103691564
Publisher
Elsevier Science
Year
1981
Weight
347 KB
Volume
10
Category
Article
ISSN
0304-5102

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Chelate complexes of the type [ Rh( q2-0,Z) (PR,),] (Z = CCH,, CCF3, CtBu, S( 0) -p-C&I&H,; PR, = PiPr,, PPhiPr,, PPh,iPr) catalyze the hydrogenation of phenylacetylene in toluene solution at 60°C. Selectivities close to 100% are achieved for the hydrogenation of the alkyne to the alkene in the pre