Kinetic studies in mass spectrometry—VIII: Competing [M CH3] and [M CH2O] reactions in substituted anisoles. Approximate activation energies from ioniziation and appearance potentals

Kinetic studies in mass spectrometry—IX:

Kinetic studies in mass spectrometry—IX: Competing [M NO2] and [M NO] reactions in substituted nitrobenzenes. Approximate activation energies from ionization and appearance potentials

✍ Peter Brown 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 569 KB

Ionization (IP) and appearance potentials (AP) have been secured for apparently competing [M - NO,] cleavage and [M -NO] rearrangement reactions in a series of mand p-X substituted nitrobenzene molecular ions. Approximate activation energies AP-IP were within the experimental reproducibility for mos