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Kinetic, structural and electrostatic aspects of the reduction of pentacyanoferrate(III) complexes by myoglobin

✍ Scribed by Elwira Ilkowska; Krzysztof Lewiński; Rudi van Eldik; Grażyna Stochel


Book ID
106232979
Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
176 KB
Volume
4
Category
Article
ISSN
1432-1327

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✍ Lu-Ming Lin; Ming-Huei Lien; Andrew Yeh 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB

## Abstract The reduction of Fe(CN)~5~L^2−^ (L = pyridine, isonicotinamide, 4,4′‐bipyridine) complexes by ascorbic acid has been subjected to a detailed kinetic study in the range of pH 1–7.5. The rate law of the reaction is interpreted as a rate determining reaction between Fe(III) complexes and t