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Kinetic, spectroscopic, and structural evidence for carbene-carbyne intermediates in carbyne/CO coupling

✍ Scribed by Protasiewicz, John D.; Masschelein, Axel; Lippard, Stephen J.


Book ID
126946190
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
419 KB
Volume
115
Category
Article
ISSN
0002-7863

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Reaction of the ylide (cyclopropyl) 3 P=CH 2 with Michler's 3Ј) or bis(p-methoxyphenyl) thioketone (to give 5), respectively. The oxaphosphetane series 3Јa-3Јc shows a thioketone S=C(C 6 H 4 NMe 2 ) 2 in [D 5 ]pyridine gave the thio Wittig intermediate [(cyclopropyl) 3 P + -CH 2 -CAr 2 -S -] (11; 31