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Kinetic Spectrophotometric Determination of Traces of Sulfite Based on Its Additional Reaction with Methyl Green

โœ Scribed by A. Jabbari; M. Shamsipur


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
252 KB
Volume
48
Category
Article
ISSN
0026-265X

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โœฆ Synopsis


A simple, rapid, and sensitive kinetic method has been developed for the determination of traces of sulfite ((0.05-2.5 \mu \mathrm{g} / \mathrm{ml})) based on the addition reaction of sulfite with methyl green at (\mathrm{pH} 8) and (25^{\circ} \mathrm{C}). The reaction is monitored spectrophotometrically by measuring the decrease in absorbance of the dyestuff at (625 \mathrm{~nm}) by the fixed time method. The limit of detection is (0.05 \mu \mathrm{g} / \mathrm{ml}) and the relative standard deviation for (0.5 \mu \mathrm{g} / \mathrm{ml}) sulfite is (2.88 %). The interfering effect of various ions was studied. The method was applied to the determination of sulfite in a number of fruit juices. 1993 Academic Press, Inc.


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