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Kinetic secondary deuterium isotope effects for substituted benzaldehyde cyanohydrin formation

✍ Scribed by Okano, Valkiria; Do Amaral, Luciano; Cordes, E. H.


Book ID
126141606
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
406 KB
Volume
98
Category
Article
ISSN
0002-7863

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## Abstract Deuterium‐induced isotope effects on ^13^C chemical shifts and ^1^__J__(^13^C‐α, ^1^H) coupling constants in benzaldehyde were measured. Over 30 different effects on ^13^C chemical shifts were revealed. The effects through one (^1^Ξ”) and two bonds (^2^Ξ”) have mean values of 282.1 Β± 9.6