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Kinetic role oft-amines in the ligand inhibited osmium tetraoxide catalyzed trimethylamine-N-oxide dihydroxylation of alkenes

✍ Scribed by Ender Erdik; Didem Kâhya


Book ID
111550615
Publisher
Springer
Year
2003
Tongue
English
Weight
127 KB
Volume
28
Category
Article
ISSN
0340-4285

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Kinetic role of tert-amines in the osmiu
✍ Ender Erdik; Didem Kâhya 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB 👁 1 views

Effect of some tert-amines on the catalytic osmium tetroxide dihydroxylation of cyclohexene in aqueous tert-butyl alcohol has been investigated. All amines have been found to retard the catalysis greatly and beyond a definite concentration of amine, the rate reaches a minimal and remains constant. T