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Kinetic Resolution of Chiral Secondary Alcohols by Dehydrogenative Coupling with Recyclable Silicon-Stereogenic Silanes

✍ Scribed by Sebastian Rendler; Gertrud Auer; Martin Oestreich

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 152 KB
Volume: 44
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200502631

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## Abstract Ligand‐stabilized copper(I)–hydride catalyzes the dehydrogenative Si–O coupling of alcohols and silanes—a process that was found to proceed without racemization at the silicon atom if asymmetrically substituted. The present investigation starts from this pivotal observation since silico