Kinetic resolution of chiral metallocenic aldehydes and alcohols with liver alcohol dehydrogenase
β Scribed by Yoshimitsu Yamazaki; Kuniaki Hosono
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 160 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Horse liver alcohol dehydrogenase-catalyzed oxidoraducticn was useful to resolve racemic lformyl-Z-methyl derivatiws of tricarbonyl(cyclopentadienyl)manganese and (benzene)tricarbonylchromium and racemic 1-hydroxyethylferrocene, ruthenocene and osmocme.
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Stereoselective dehydrogenation of three isomers of trimethylsilylpropanol was carried out with horse liver alcohol dehydrogenase (HLADH, EC 1.1.1.1.) and optically active organosilicon compounds were obtained in a water-organic solvent two-layer system with coenzyme regeneration. Furthermore, we ex
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