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Kinetic resolution and isomerization of 2,5-disubstituted pyrrolines

✍ Scribed by Jaesook Yun; Stephen L. Buchwald

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
112 KB
Volume
12
Category
Article
ISSN
0899-0042

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✦ Synopsis

The efficient kinetic resolution of 2,5-disubstituted pyrrolines was accomplished by employing hydrosilylation with a chiral catalyst, (EBTHI)TiF2 (EBTHI = ethylenebis(tetrahydroindenyl)). An interesting isomerization reaction of the cyclic imines catalyzed by the same chiral catalyst was also discovered.

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