Kinetic protium-deuterium isotope effect in an intramolecular 1–5 shift of hydrogen
✍ Scribed by H. Kloosterziel; A. P. ter Borg
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 432 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0165-0513
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The interesting deuterium isotope e †ects of gossypols have been reinvestigated and the very large two-bond isotope e †ect, 2DC-6(OD), is ascribed to electric Ðeld e †ects. Common to the investigated compounds is the presence of intramolecular hydrogen bonds. A feature strongly related to the streng
The thermal unimolecular decomposition of diethyl carbonate-1,1,1,2,2-d5 has been examined in the high-pressure-limiting region. The observed chemistry is consistent with a simple, competitive two-channel model: The intramolecular isotope effect k H / k D has been determined, and the relative Arrhe
## Abstract A new class of compounds, the 2‐hydroxythioacetophenones, and related compounds have recently been synthesized. The hydrogen‐bond system has been characterized by NMR chemical shifts and deuterium isotope effects on these as well as by DFT calculations. Use of solid‐state ^13^C NMR has