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Kinetic partitioning mechanism as a unifying theme in the folding of biomolecules

✍ Scribed by D. Thirumalai; D. K. Klimov; S. A. Woodson

Publisher
Springer
Year
1997
Tongue
English
Weight
376 KB
Volume
96
Category
Article
ISSN
1432-2234

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Kinetics and mechanism of ligand exchange of coordinated cyanide in hexacyanoferrate(II) by nitroso-R-salt in the presence of mercury(II) as a catalyst
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## Abstract The kinetics of Hg(II)‐catalyzed reaction between hexacyanoferrate(II) and nitroso‐R‐salt has been followed spectrophotometrically by monitoring the increase in absorbance at 720 nm, the Ξ»~max~ of green complex, [Fe(CN)~5~ N‐R‐salt]^3βˆ’^ as a function of pH, ionic strength, temperature,