Kinetic parameters of unsaturated polyester resin modified with poly(ε -caprolactone)
✍ Scribed by J. Escribano; R. Masegosa; D. Nava; M. G. Prolongo; Catalina Salom
- Publisher
- Springer Netherlands
- Year
- 2006
- Tongue
- English
- Weight
- 269 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0022-5215
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A study has been made of the isothermal crystallization kinetics of poly(caprolactone) (PCL) in partially miscible crosslinked polyester resin (PER)/PCL blends by using differential scanning calorimetry (DSC). For comparison, miscible blends of PCL with uncured polyester resin, i.e., oligoester resi
## Abstract Titanium alkoxides are widely used in the ring‐opening polymerization of ε‐caprolactone. In this study, functional poly(ε‐caprolactone) was synthesized with a new titanium initiator by a two‐step procedure: First, the titanium initiator, with an unsaturated group, was prepared by a clas