## Abstract A chain mechanism is proposed to account for the very rapid termination reactions observed between alkyl peroxy radicals containing Ξ±βCβH bonds which are from 10^4^ to 10^6^ faster than the termination of tertiary alkyl peroxy radicals. The new mechanism is equation image with termina
Kinetic Parameters of Alkyl, Alkoxy, and Peroxy Radical Isomerization
β Scribed by T. G. Denisova; E. T. Denisov
- Book ID
- 110312325
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 84 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0023-1584
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Alkyl, (CH3)3COC(CH3)2CH2, and alkyl peroxy, (CH3)3COC(CH3)2CH202, radicals from di-tert-butyi ether (DTBE), have been studied in the gas phase at 296 K. A pulse radiolysis UV absorption technique was used to measure the spectra and kinetics. Absorption cross sections were quantified over the wavele
Alkyl and alkyl peroxy radicals from t-butyl alcohol (TBA), HOC(CH,),CH; and HOC(CH9)&H20i have been studied in the gas phase at 298 K. Two techniques were used: pulse radiolysis UV absorption to measure the spectra and kinetics, and long path-length Fourier transform infrared spectroscopy (FTIR) to