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Kinetic parameters from temperature-programmed reactions: The pyrolysis of polytetrafluoroethylene

✍ Scribed by Benjamin Carroll; Emanuel P. Manche

Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
369 KB
Volume
9
Category
Article
ISSN
0021-8995

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An evaluation of the kinetic parameters
An evaluation of the kinetic parameters for the reaction of trifluoromethyl radicals with CH3Cl in the gas phase in the temperature range from 416 to 636 K
✍ R. A. Taccone; A. Olleta; O. Salinovich πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 479 KB πŸ‘ 1 views

The hydrogen and chlorine atom abstraction reactions from CH3CI by CF3 radicals produced by the photolysis of hexafluoroacetone (HFA) and CF31 were studied relative to the recombination of CF3 radicals: The Arrhenius parameters obtained in the temperature range 416 to 578 K are: Log k3/k:/\*[cm3/\*