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Kinetic NMR and Density Functional Study of Benzene H/D Exchange in Zeolites, the Most Simple Aromatic Substitution

✍ Scribed by Beck, Larry W.; Xu, Teng; Nicholas, John B.; Haw, James F.


Book ID
120016874
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
791 KB
Volume
117
Category
Article
ISSN
0002-7863

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Electrophilic aromatic substitution. 14.
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Vacuum line kinetic studies of the reaction of p-toluenesulfonyl chloride and benzene or toluene, using aluminum chloride as the catalyst and dichloromethane as the solvent were determined at 25ЊC by means of gas chromatography. The reaction is first-order in arene, tosyl chloride, and in AlCl 3 as