Kinetic models of multi-route reactions in homogeneous catalysis with metal complexes (A Review)
โ Scribed by Temkin, O. N.
- Book ID
- 114989584
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 911 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0023-1584
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๐ SIMILAR VOLUMES
Nickel complexes are found to be catalytically active in the cross-coupling reactions of allenic bromides with alkyl metals to give substituted allenes in excellent yields. The catalytic process proceeds generally with inversion of configuration in the allenyl moiety.
A kinetic study of the displacement of cycloheptatriene from I($-C,H8)M(CO)J (M = 0, MO. W) by benzonitrile shows unusual changes in rate law down the triad. While the chromium complex obeys the second-order rate law Rate = k[complex] [RCN] , the molybdenum species follows the third-order law Rate =