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Kinetic Modeling of the Effect of H 2 S and of NH 3 on Toluene Hydrogenation in the Presence of a NiMo/Al 2 O 3 Hydrotreating Catalyst. Discrimination between Homolytic and Heterolytic Models

✍ Scribed by Blanchin, S.; Galtier, P.; Kasztelan, S.; Kressmann, S.; Penet, H.; Pérot, G.

Book ID
121279212
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
92 KB
Volume
105
Category
Article
ISSN
1089-5639

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The toluene hydrogenation performances of MO-and NiMo-A1203 hydrotreating catalysts are modified by vanadium deposited through HDM of the Vanadylporphyrin. Bulk deposited vanadium sulfide of mean VS 1 .l stoichiometry does not greatly affect the intrinsic performances of the initial catalysts but i