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Kinetic Modeling of Ethylene−Norbornene Copolymerization Using Homogeneous Metallocene Catalysts

✍ Scribed by Park, Seung Young; Choi, Kyu Yong; Song, Kwang Ho; Jeong, Boong Goon

Book ID
126305272
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
145 KB
Volume
36
Category
Article
ISSN
0024-9297

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Copolymerization of ethylene with a symmetrical diene, namely, 2,5-norbornadiene was studied using a homogeneous metallocene/MAO catalyst system. Copolymerizations were found to occur exclusively through one of the two equally reactive endocyclic double bonds with Cp 2 ZrCl 2 , (buCp) 2 ZrCl 2 and E