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Kinetic Model for the Reaction of Cobalt Porphyrins with Olefins under Free Radical Conditions 1

✍ Scribed by Gridnev, Alexei A.; Ittel, Steven D.; Fryd, Michael; Wayland, Bradford B.


Book ID
126869109
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
395 KB
Volume
15
Category
Article
ISSN
0276-7333

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## Abstract Rate constants for the reactions of OH radicals and Cl atoms with 1‐propanol (1‐C~3~H~7~OH) have been determined over the temperature range 273–343 K by the use of a relative rate technique. The value of __k__(Cl + 1‐C~3~H~7~OH) = (1.69 Β± 0.19) Γ— 10^βˆ’12^ cm^3^ molecule^βˆ’1^ s^βˆ’1^ at 298