Kinetic methods of analysis

✍ Scribed by J. Gordon Hanna; Sidney Siggia

• Book ID: 102913926
• Publisher: John Wiley and Sons
• Year: 1966
• Tongue: English
• Weight: 870 KB
• Volume: 55
• Category: Article
• ISSN: 0022-3549
• DOI: 10.1002/jps.2600550602

✦ Synopsis

Because he can he satisfied with no less than quantitative recoveries, he must utilize optimum cxperimcnt.al conditions for his reactions. He uses these conditions not only to produce the desired stoichiometric reaction in the minimum time but also t C J obtain a specific reaction with the least interference from side or parallel reactions. Analytical chemists have gone a step further and are applying the kincticists' reaction rate techniques directlJ-to the solution of analytical prohlems. This has yielded methods which give quantitative results based on reactions which are

In fact, some methods require the occurrence of only a small fraction of the reaction. Also, procedures have been developed for the determination of traces of materials based on their catalytic effect on the rates of suitable reactions. Another result is the production of mcthods for the differential determination of two or more compounds in a. mixture which are reacting concurrently but a t different rates with a common reagent. l'hese developments in the use of reaction rate approaches are considered in this review.

K'" prime importance to the analytical chemist rily complete.