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Kinetic mechanism of the reaction of NH2with O2in O-, H-, and N-containing flames. II. Estimation of kinetic parameters of the stages involving NH2O2, HNOOH, and NH2O

โœ Scribed by N. E. Ermolin; O. P. Korobeinichev; V. M. Fomin


Publisher
SP MAIK Nauka/Interperiodica
Year
1994
Tongue
English
Weight
469 KB
Volume
30
Category
Article
ISSN
0010-5082

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๐Ÿ“œ SIMILAR VOLUMES


Kinetics of the reactions OH (v = O) + N
โœ Michael J. Kurylo ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 400 KB

The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u

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โœ Edwin J. Hamilton Jr.; Ruey-Rong Lii ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 538 KB

Electron pulse radiolysis a t -298'K of 2 atm Hz containing 5 torr 0 2 produces HOz free radical whose disappearance by reaction (I), HOz + HOz -HzOz + 0 2 , is monitored by kinetic spectrophotometry a t 230.5 nm. Using a literature value for the HOz absorption cross section, the values k = 2.5 X cm