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Kinetic mechanism of caprolactam polymerization

✍ Scribed by B. Sh. Khaitin; L. A. Vol'f

Book ID
104804527
Publisher
Springer US
Year
1977
Tongue
English
Weight
249 KB
Volume
9
Category
Article
ISSN
0015-0541

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## Abstract A method to determine the concentration of ϵ‐aminocaproic acid (ACA) in poly‐ϵ‐caprolactam by high‐pressure liquid chromatography is established. The polymerizations for initial water concentrations of 0.42, 0.82, and 1.18 mol/kg and temperatures of 230, 240, 250, 260, 270, and 280°C we

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## NOPSlS In this study, bis t-caprolactam bis-diphenyl methane diisocyanate polypropylene glycol 1000 used as the macroactivator was prepared and well characterized prior to use. The anionic polymerization of e-caprolactam with the macroactivator as a function of the macroactivator concentration