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Kinetic Isotope Effects and exo/endo-Face Selectivity in the Unimolecular Dehydrogenation of Norborneol Alkoxides in the Gas Phase

✍ Scribed by Uwe Dreyer; Detlev Sülzle; Detlel Schröder; Helmut Schwarz

Publisher
John Wiley and Sons
Year
1990
Tongue
German
Weight
203 KB
Volume
73
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The study of specifically labeled alkoxides generated in the gas phase by deprotonation of epimeric norbernols demonstrates, beyond any doubt, that ‘solvated’ hydride ions are formed as intermediates in the course of enolate formation. Kinetic isotope effects and exo/endo‐face selectivities for the dehydrogenation are discussed.

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