Kinetic Investigations of the Metallocene – Catalyzed Polymerization of Ethylene at High Pressure
✍ Scribed by A. Rau; S. Schmitz; G. Luft
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 283 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0930-7516
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Norbornene-ethylene copolymers were prepared using the metallocene catalyst ethylene bis (indenyl) zirconium dichloride with MAO, and their microstructure was characterized with 1 H-NMR and 13 C-NMR methods. From a Cosy 1 H-NMR spectrum it was found that all norbornene units are enchained in the exo
Stereospecific polymerization of 1-hexene under high pressures (up to 1,000 MPa ϭ ca. 10,000 atm) using metallocene/methylaluminoxane (MAO) catalysts was investigated. Several C 2 -symmetric ansa-metallocenes, their meso-isomers, and two C s -symmetric ansa-metallocenes were employed as catalyst pre