Kinetic investigation on thermal decomposition of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) nanoparticles
✍ Scribed by M. Fathollahi; B. Mohammadi; J. Mohammadi
- Book ID
- 119240374
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 901 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0016-2361
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## Abstract Thermal decomposition of KDX has been studied by Differential Scanning Calorimetry. KDX was found to decompose significantly below its melting point. The rate and activation energy (E) of the decomposition in the open and closed‐pan conditions were different. Under closed‐pan conditions
## Abstract ^14^C‐labeled hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (2, RDX) was prepared by nitrolysis of hexahydro‐1,3,5‐tripropionyl‐1,3,5‐triazine (1) for bioenvironmental studies. 1 was synthesized from paraformaldehyde and propionitrile by a modified method reported earlier.
The thermal decomposition of RDX has been investigated in a static system below its melting point at ~ 195°(?. "the initial decomp<~,ition of RDX takes place in the vapor phase. Ilydroxymethyl [ormamidc and polymeric materials tbrmed from hydroxymethyl formamide have been shown to be major products.