𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic instabilities in heterogeneously catalyzed reactions—I: Rate multiplicity with langmuir-type kinetics

✍ Scribed by Gerhart Eigenberger

Book ID
103005607
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
579 KB
Volume
33
Category
Article
ISSN
0009-2509

No coin nor oath required. For personal study only.

✦ Synopsis

Ab&nct

-The questlon under which condltlons kmetlc rnstabllltles can bc described by Langmulr type kmetlcs IS studied using a fairly general model for the surface reactlon pA+qB= C This paper IS concerned with the occurrence of rate multrphclties (Igrutron-extmction phenomena)

📜 SIMILAR VOLUMES

Kinetics and mechanisms of substitution
Kinetics and mechanisms of substitution reactions with sulfur-containing nucleophiles in aqueous acid solutions. I—rates of reactions of some tetrahalopalladate (II) anions with thiourea and selenourea
✍ P. Van Z. Bekker; W. Robb 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 545 KB

## Abstract The activation energy parameters for the reaction of PdX (X=Cl^−^, Br^−^) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each cas